The Cyclization of Diethyl 3,6-Dioxo-azelate
نویسندگان
چکیده
منابع مشابه
The Cyclization of Natural Rubber
The effects of solvent, temperature, time, weight percent of catalyst on the rate and mechanism of cyclization of natural rubber (NR) was studied in toluene and xylene solutions having tin tetra chloride catalyst (SnCl4). Iodometric titration show, with 8% SnCl4 (based on polymer weight) cyclization occurs, leaving 27.4% of the total unsaturation. Infrared spectra of c...
متن کاملDiethyl 1,1-dioxo-3,5-bis(pyridin-2-yl)-1λ6,4-thiomorpholine-2,6-dicarboxylate
The title compound, C(20)H(23)N(3)O(6)S, crystallizes with two crystallographically independent mol-ecules in the asymmetric unit. The thio-morpholine ring in both mol-ecules adopts a chair conformation. The crystal structure is stabilized by C-H⋯O inter-actions. The amino groups are shielded and, as a result, these groups are not involved in hydrogen bonding.
متن کاملN,N-Diethyl-2-hydroxyethanaminium 2,6-dioxo-5-(2,4,6-trinitrophenyl)-1,2,3,6-tetrahydropyrimidin-4-olate dihydrate
In the title mol-ecular salt, C(6)H(16)NO(+)·C(10)H(4)N(5)O(9) (-)·2H(2)O, which crystallizes as a dihydrate, O-H⋯O hydrogen bonds link the barbiturate anion, the ethanaminium cation and the water mol-ecules of crystallization. The dihedral angle between the rings in the anion is 43.71 (8)°. In the crystal, an R(2) (2)(8) ring motif hydrogen-bonding pattern is also found involving inversion-rel...
متن کاملthe cyclization of natural rubber
the effects of solvent, temperature, time, weight percent of catalyst on the rate and mechanism of cyclization of natural rubber (nr) was studied in toluene and xylene solutions having tin tetra chloride catalyst (sncl4). iodometric titration show, with 8% sncl4 (based on polymer weight) cyclization occurs, leaving 27.4% of the total unsaturation. infrared spectra of cyclized nr show decreased ...
متن کاملPyridinium 5-[(1,3-diethyl-6-hydroxy-4-oxo-2-thioxo-1,2,3,4-tetrahydropyrimidin-5-yl)(2-methoxyphenyl)methyl]-1,3-diethyl-4,6-dioxo-2-thioxopyrimidin-5-ide
1,3-Diethyl-2-thio-barbituric acid reacts with 2-anisaldehyde to form the Michael addition product 2-anisylbis(1,3-diethyl-2-thio-barbitur-5-yl)methanate, which crystallizes as the title pyridin-ium salt, C(5)H(6)N(+)·C(24)H(29)N(4)O(5)S(2) (-), when it reacts with the pyridine used to catalyse the reaction. There are two independent ion pairs in the crystal structure. The anion features a meth...
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1965
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.38.255